Correlation between oxygen evolution reaction activity and surface compositional evolution in epitaxial La0.5Sr0.5Ni1−xFexO3−δ thin films

Author:

Adiga Prajwal1,Wang Le2ORCID,Wong Cindy1,Matthews Bethany E.3,Bowden Mark E.4ORCID,Spurgeon Steven R.35ORCID,Sterbinsky George E.6,Blum Monika78,Choi Min-Ju2,Tao Jinhui2,Kaspar Tiffany C.2ORCID,Chambers Scott A.2,Stoerzinger Kelsey A.12ORCID,Du Yingge2

Affiliation:

1. School of Chemical, Biological and Environmental Engineering, Oregon State University, Corvallis, Oregon, 97331, USA

2. Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99354, USA

3. Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352, USA

4. Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, Washington 99352, USA

5. Department of Physics, University of Washington, Seattle, Washington 98195, USA

6. Advanced Photon Source, Argonne National Laboratory, Lemont, Illinois 60439, USA

7. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

8. Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA

Abstract

A Ni–Fe based perovskite oxide catalyzes the oxygen evolution reaction (OER), coupled with changes in local composition and structure identified by virtue of an epitaxial thin film geometry.

Funder

Oregon State University

Link Foundation

National Science Foundation

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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