Zirconium arene triple-decker sandwich complexes: synthesis, electronic structure and bonding-Reference-Cited by-同舟云学术

Zirconium arene triple-decker sandwich complexes: synthesis, electronic structure and bonding

Published:2017 Issue:88 Volume:53 Page:12048-12051
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kilpatrick A. F. R.¹²³⁴⁵^ORCID,Green J. C.⁶³⁴⁵,Turner Z. R.¹²³⁴⁵^ORCID,Buffet J.-C.¹²³⁴⁵^ORCID,O’Hare D.¹²³⁴⁵^ORCID

Affiliation:

1. Chemistry Research Laboratory

2. Department of Chemistry

3. University of Oxford

4. Oxford

5. UK

6. Inorganic Chemistry Laboratory

Abstract

Reduction of a permethylpentalene zirconium(iv) chloride complex [η⁸-Pn*Zr(μ-Cl)_3/2]₂(μ-Cl)₂Li·THF_xwith KC₈in benzene results in activation of the aromatic solvent to yield an “inverted sandwich” complex, [η⁸-Pn*Zr]₂(μ-η⁶:η⁶-C₆H₆) (1).

Funder

SCG Chemicals

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC07083G

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