Thyminate(2−)-bridged cyclic tetranuclear rhodium(iii) complexes formed by a template of a sodium, calcium or lanthanoid ion-Reference-Cited by-同舟云学术

Thyminate(2−)-bridged cyclic tetranuclear rhodium(iii) complexes formed by a template of a sodium, calcium or lanthanoid ion

Published:2015 Issue:10 Volume:51 Page:1889-1892
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kashima Ayana¹²³⁴⁵,Sakate Mika¹²³⁴⁵,Ota Hiromi⁶³⁴⁵,Fuyuhiro Akira¹⁷⁸⁹⁵,Sunatsuki Yukinari¹²³⁴⁵,Suzuki Takayoshi¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. Okayama University

4. Okayama 700-8530

5. Japan

6. Advanced Science Research Centre

7. Graduate School of Science

8. Osaka University

9. Toyonaka 560-0043

Abstract

In the homochirally aggregated tetranuclear Cp*Rh^III complexes, the bridging mode of thyminate(2−) was dependent on the template cation: μ₃-1κN¹:2κ²N³,O²:3κO² in the Na⁺ and Ca²⁺ complexes and μ₃-1κN¹:2κ²N³,O⁴:3κO² in the Ln³⁺ analogues.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C4CC09087J

Reference32 articles.

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4. Structural and Functional Evolution of Metallacrowns

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