Post-synthetic modification of zirconium metal–organic frameworks by catalyst-free aza-Michael additions
Author:
Affiliation:
1. Department of Chemistry
2. University of Bath
3. Bath BA2 7AY
4. UK
Abstract
UiO-66-NH2 reacts with acrylonitrile, acrylic acid, methyl acrylate and methyl vinyl ketone leading to post-synthetic modification of the MOF through C–N bond formation. The acrylonitrile-modified MOF undergoes further reaction to form a tetrazolate-modified MOF.
Funder
University of Bath
Majlis Amanah Rakyat
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03312A
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