Gigantic work function in layered AgF2

Author:

Wegner Wojciech12345ORCID,Tokár Kamil678910,Lorenzana Jose1112131415ORCID,Derzsi Mariana521646ORCID,Grochala Wojciech52164ORCID

Affiliation:

1. College of Inter-Faculty Individual Studies in Mathematics and Natural Sciences

2. University of Warsaw

3. 02-097 Warsaw

4. Poland

5. Center of New Technologies

6. Advanced Technologies Research Institute

7. Faculty of Materials Science and Technology in Trnava

8. Slovak University of Technology in Bratislava

9. 917 24 Trnava

10. Slovakia

11. Institute for Complex Systems (ISC)

12. Consiglio Nazionale delle Ricerche

13. Dipartimento di Fisica

14. Universita di Roma “La Sapienza”

15. 00185 Rome

16. 02-089 Warsaw

Abstract

The calculated work function of a powerful oxidizer, AgF2, is 7.76 eV, thus exceeds even that of fluorinated diamond. This unusual property could be used for fabrication of novel junction electronic devices showing ‘‘broken-gap’’ type band alignment.

Funder

Narodowe Centrum Nauki

European Regional Development Fund

Agentúra na Podporu Výskumu a Vývoja

Ministero dell’Istruzione, dell’Università e della Ricerca

Regione Lazio

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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