How solvents affect the stability of cationic Rh(<scp>i</scp>) diphosphine complexes: a case study of MeCN coordination-Reference-Cited by-同舟云学术

How solvents affect the stability of cationic Rh(i) diphosphine complexes: a case study of MeCN coordination

Published:2022 Issue:47 Volume:51 Page:18068-18076
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jannsen Nora¹^ORCID,Fischer Christian²^ORCID,Selle Carmen¹,Pribbenow Cornelia¹,Drexler Hans-Joachim¹^ORCID,Reiß Fabian¹^ORCID,Beweries Torsten¹^ORCID,Heller Detlef¹

Affiliation:

1. Leibniz Institut für Katalyse e.V., Albert-Einstein-Straße 29a, 18059 Rostock, Germany

2. Universität Greifswald, Institut für Biochemie, Felix Hausdorff-Straße 4, 17489 Greifswald, Germany

Abstract

We present a method for the systematic investigation and quantification of the stability of solvate complexes of the type [Rh(diphosphine)(solvent)2]+, using MeCN which replaces diolefins and forms stable Rh(i) MeCN complexes.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT03583A

Reference68 articles.

1. Preparation and catalytic properties of some cationic iridium(III) and rhodium(III) dihydrido complexes

2. Coordinatively unsaturated cationic complexes of rhodium(I), iridium(I), palladium(II), and platinum(II). Generation, synthetic utility, and some catalytic studies

3. Catalytic hydrogenation using cationic rhodium complexes. I. Evolution of the catalytic system and the hydrogenation of olefins

4. Catalytic hydrogenation using cationic rhodium complexes. 3. The selective hydrogenation of dienes to monoenes

5. K.Tanaka , Rhodium Catalysis in Organic Synthesis: Methods and Reactions , Wiley-VCH Verlag GmbH & Co. KGaA , Weinheim, Germany , 2019

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