Towards dipyrrins: oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes-Reference-Cited by-同舟云学术

Towards dipyrrins: oxidation and metalation of acyclic and macrocyclic Schiff-base dipyrromethanes

Published:2015 Issue:5 Volume:44 Page:2066-2070
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pankhurst James R.¹²³⁴,Cadenbach Thomas¹²³⁴,Betz Daniel¹²³⁴,Finn Colin¹²³⁴,Love Jason B.¹²³⁴

Affiliation:

1. EaStCHEM School of Chemistry

2. University of Edinburgh

3. Edinburgh

4. UK

Abstract

Oxidation of acyclic Schiff-base dipyrromethanes cleanly results in dipyrrins, whereas the macrocyclic ‘Pacman’ analogues either decompose or form new dinuclear copper(ii) complexes that are inert to ligand oxidation.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03592E

Reference45 articles.

1. Metal-mediated transformations of small molecules

2. Toward Functional Carboxylate-Bridged Diiron Protein Mimics: Achieving Structural Stability and Conformational Flexibility Using a Macrocylic Ligand Framework

3. Electrocatalytic CO 2 Conversion to Oxalate by a Copper Complex

4. A Cytochrome c Oxidase Model Catalyzes Oxygen to Water Reduction Under Rate-Limiting Electron Flux

5. Molecular Chemistry of Consequence to Renewable Energy

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