Understanding the modulation effect and surface chemistry in a heteroatom incorporated graphene-like matrix toward high-rate lithium–sulfur batteries-Reference-Cited by-同舟云学术

Understanding the modulation effect and surface chemistry in a heteroatom incorporated graphene-like matrix toward high-rate lithium–sulfur batteries

Published:2021 Issue:35 Volume:13 Page:14777-14784
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Zhao Zhenxin¹,Yi Zonglin²³,Li Huijun¹^ORCID,Pathak Rajesh⁴,Cheng Xiaoqin¹,Zhou Junliang¹,Wang Xiaomin¹^ORCID,Qiao Qiquan⁵^ORCID

Affiliation:

1. College of Materials Science and Engineering, Shanxi Key Laboratory of New Energy Materials and Devices, Taiyuan University of Technology, Taiyuan, 030024, PR China

2. CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, 030001, PR China

3. University of Chinese Academy of Sciences, Beijing, 100049, PR China

4. Applied Materials Division, Argonne National Laboratory, Lemont, IL, 60439, USA

5. Mechanical & Aerospace Engineering, Syracuse University, Syracuse, NY 13244, USA

Abstract

The graphene-like carbon network helps in improving the affinity for polysulfides and reduces the shuttle effect. Nitrogen and phosphorus act as bifunctional active sites and further reduce the activation energy, leading to superior rate capability.

Funder

National Natural Science Foundation of China

ShanXi Science and Technology Department

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NR/D1NR03390E

Reference57 articles.

1. Fluorinated hybrid solid-electrolyte-interphase for dendrite-free lithium deposition

2. A high-energy and long-cycling lithium–sulfur pouch cell via a macroporous catalytic cathode with double-end binding sites