Can a pentamethylcyclopentadienyl ligand act as a proton-relay in f-element chemistry? Insights from a joint experimental/theoretical study-Reference-Cited by-同舟云学术

Can a pentamethylcyclopentadienyl ligand act as a proton-relay in f-element chemistry? Insights from a joint experimental/theoretical study

Published:2015 Issue:6 Volume:44 Page:2575-2587
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kefalidis Christos E.¹²³⁴⁵,Perrin Lionel⁶⁷⁸⁹⁵,Burns Carol J.¹⁰¹¹¹²,Berg David J.¹³¹⁴¹⁵¹⁶,Maron Laurent¹²³⁴⁵,Andersen Richard A.¹³¹⁷¹⁸¹²

Affiliation:

1. LPCNO

2. CNRS & INSA

3. Université Paul Sabatier

4. Toulouse 31077

5. France

6. Université Lyon 1

7. CNRS UMR 5246

8. Institut de Chimie et Biochimie Moléculaires et Supramoléculaires

9. F-69622 Villeurbanne

10. Los Alamos National Laboratory

11. Los Alamos

12. USA

13. Department of Chemistry

14. University of Victoria

15. Victoria

16. Canada V8W 3V6

17. University of California

18. Berkeley

Abstract

Isomerisation of buta-1,2-diene to but-2-yne by (Me₅C₅)₂Yb is a thermodynamically favourable reaction, with the Δ_rG° estimated from experimental data at 298 K to be −3.0 kcal mol⁻¹.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02387K

Reference99 articles.

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4. Methane exchange reactions of lanthanide and early-transition-metal methyl complexes

5. Quantum Chemical Characterization of Methane Metathesis in L2MCH3 (L = H, Cl, Cp, Cp*; M = Sc, Y, Lu)

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