Experimental and theoretical investigation of oxidative methane activation on Pd

Experimental and theoretical investigation of oxidative methane activation on Pd–Pt catalysts

Published:2019 Issue:20 Volume:9 Page:11385-11395
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Qi Wenjie¹²³⁴⁵^ORCID,Huang Zehao¹²³⁴⁵,Chen Zheming¹²³⁴⁵,Fu Lijuan¹²³⁴⁵,Zhang Zhigang¹²³⁴⁵

Affiliation:

1. Key Laboratory of Advanced Manufacturing Technology for Automobile Parts

2. Ministry of Education

3. Chongqing University of Technology

4. Chongqing 400050

5. China

Abstract

Density functional theory and measurements of rate are used to provide evidence for the rate determining step and requirements of the active site for CH₄ combustion on Pd–Pt bimetallic catalysts in five different distinct kinetic regimes.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA00735K

Reference34 articles.

1. Pathways and kinetics of methane and ethane C–H bond cleavage on PdO(101)

2. Molecular understandings on the activation of light hydrocarbons over heterogeneous catalysts

3. First-Principles Investigation of C–H Bond Scission and Formation Reactions in Ethane, Ethene, and Ethyne Adsorbed on Ru(0001)

4. High Selectivity for Primary C–H Bond Cleavage of Propane σ-Complexes on the PdO(101) Surface

5. Characterisation and microstructure of Pd and bimetallic Pd–Pt catalysts during methane oxidation

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis of surface-engineered SrFe2O4 for efficient catalytic partial oxidation of methane;Sustainable Chemistry for Climate Action;2024-12

2. Plasmon-Driven Selective Methane Oxidation to Formic Acid at Ambient Conditions;ACS Energy Letters;2024-01-23