Origin of intersystem crossing in highly distorted organic molecules: a case study with red light-absorbingN,N,O,O-boron-chelated Bodipys-Reference-Cited by-同舟云学术

Origin of intersystem crossing in highly distorted organic molecules: a case study with red light-absorbingN,N,O,O-boron-chelated Bodipys

Published:2023 Issue:19 Volume:14 Page:5014-5027
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Xue¹^ORCID,Sukhanov Andrey A.²^ORCID,Liu Xi³,Taddei Maria⁴,Zhao Jianzhang¹^ORCID,Harriman Anthony⁵^ORCID,Voronkova Violeta K.²^ORCID,Wan Yan³^ORCID,Dick Bernhard⁶^ORCID,Di Donato Mariangela⁴⁷^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals, Frontiers Science Center for Smart Materials, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China

2. Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of Russian Academy of Sciences, Kazan 420029, Russia

3. College of Chemistry, Beijing Normal University, Beijing 100875, P. R. China

4. LENS (European Laboratory for Non-Linear Spectroscopy), Via N. Carrara 1, 50019 Sesto Fiorentino (FI), Italy

5. Molecular Photonics Laboratory, School of Natural and Environmental Sciences, Newcastle University, Newcastle Upon Tyne, NE1 7RU, UK

6. Lehrstuhl für Physikalische Chemie, Institut für Physikalische und Theoretische Chemie, Universität Regensburg, D-93053 Regensburg, Germany

7. ICCOM, Istituto di Chimica dei Complessi OrganoMetallici, Via Madonna del Piano 10, 50019 Sesto Fiorentino (FI), Italy

Abstract

A twisted π-conjugated framework does not necessarily promote efficacious ISC, energy matching of S1/Tnexcited states offers a more promising route to triplet enhancement.

Funder

National Natural Science Foundation of China

Dalian University of Technology

Fundamental Research Funds for the Central Universities

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00854A

Reference123 articles.