N-Allenylnitrone acts as 2-azadiene in the Cu-catalyzed cascade reaction of O-propargylic oximes with azodicarboxylates-Reference-Cited by-同舟云学术

N-Allenylnitrone acts as 2-azadiene in the Cu-catalyzed cascade reaction of O-propargylic oximes with azodicarboxylates

Published:2014 Issue:8 Volume:1 Page:914-918
ISSN:2052-4129
Container-title:Org. Chem. Front.
language:en
Short-container-title:Org. Chem. Front.

Author:

Nakamura Itaru¹²³⁴,Jo Takeru⁵²³⁴,Zhang Dong⁵²³⁴,Terada Masahiro¹²³⁴⁵

Affiliation:

1. Research and Analytical Center for Giant Molecules

2. Graduate School of Science

3. Tohoku University

4. Sendai 980-8578, Japan

5. Department of Chemistry

Abstract

Cu-catalyzed reaction between O-propargylic oximes and azodicarboxylates proceeded via 2,3-rearrangement followed by [4 + 2] cycloaddition, in which N-allenylnitrone acts as 2-azadiene.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/QO/C4QO00156G

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