Tuning PNIPAm self-assembly and thermoresponse: roles of hydrophobic end-groups and hydrophilic comonomer
Author:
Affiliation:
1. Department of Chemistry
2. University of Minnesota
3. Minneapolis
4. USA
5. Departments of Chemical Engineering and Materials Science
Abstract
Systematic study of hydrophobic and hydrophilic modifications to poly(N-isopropylacrylamide) elucidates design rules for control over cloud point and aqueous self-assembly.
Funder
Dow Chemical Company
National Science Foundation
University of Minnesota
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering
Link
http://pubs.rsc.org/en/content/articlepdf/2019/PY/C9PY00180H
Reference48 articles.
1. Poly(N-isopropylacrylamide): experiment, theory and application
2. Thermal Response of Narrow-Disperse Poly(N-isopropylacrylamide) Prepared by Atom Transfer Radical Polymerization
3. Comparison of the Coil-to-Globule and the Globule-to-Coil Transitions of a Single Poly(N-isopropylacrylamide) Homopolymer Chain in Water
4. Phase transition of aqueous solutions of poly(N-isopropylacrylamide) and poly(N-isopropylmethacrylamide)
5. Poly( N ‐isopropylacrylamide) Phase Diagrams: Fifty Years of Research
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