History, versatility and future prospects of oscillatory carbonylation reactions of alkynes

Author:

Novakovic Katarina1234ORCID,Bruk Lev567,Temkin Oleg567

Affiliation:

1. School of Engineering

2. Newcastle University

3. Newcastle upon Tyne

4. UK

5. MIREA-Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)

6. Moscow

7. 119571 Russia

Abstract

The BT-GN reactions are versatile chemical oscillators, oscillating in pH, redox potential and turbidity, and releasing heat in a pulsatile manner. The reaction system has a potential to be coupled with intelligent materials and yield applications.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference36 articles.

1. New Oscillating Reaction in Catalysis by Metal Complexes:  A Mechanism of Alkyne Oxidative Carbonylation

2. Achieving pH and Qr oscillations in a palladium-catalysed phenylacetylene oxidative carbonylation reaction using an automated reactor system

3. G. M.Shulyakovskii , O. N.Temkin , N. V.Bykanova and A. N.Nyrkova , in Khimicheskaya kinetika i kataliz: Kineticheskie modeli zhidkofaznykh reaktsii (Chemical Kinetics in Catalysis: Kinetic Models of Liquid-Phase Reactions) , ed. S. L. Kiperman , Chernogolovka , 1985 , p. 112

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