Multistep synthesis and X-ray structures of carboxyl-terminated hybrid iron(<scp>ii</scp>) phthalocyaninatoclathrochelates and their postsynthetic transformation into polytopic carboranyl-containing derivatives-Reference-Cited by-同舟云学术

Multistep synthesis and X-ray structures of carboxyl-terminated hybrid iron(ii) phthalocyaninatoclathrochelates and their postsynthetic transformation into polytopic carboranyl-containing derivatives

Published:2023 Issue:12 Volume:52 Page:3884-3895
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chuprin Alexander S.¹^ORCID,Pavlov Alexander A.¹²^ORCID,Vologzhanina Anna V.¹^ORCID,Dorovatovskii Pavel V.³^ORCID,Makarenkov Anton V.¹,Ol’shevskaya Valentina A.¹^ORCID,Dudkin Semyon V.¹^ORCID,Voloshin Yan Z.¹⁴^ORCID

Affiliation:

1. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 28-1 Vavilova st., 119334 Moscow, Russia

2. BMSTU Center of National Technological Initiative “Digital Material Science: New Material and Substances”, Bauman Moscow State Technical University, 2nd Baumanskaya st. 5, 105005, Moscow, Russia

3. National Research Center Kurchatov Institute, 1 Kurchatova pl., 123098, Moscow, Russia

4. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, 31 Leninsky pr., 119991 Moscow, Russia

Abstract

A multistep general synthetic strategy towards polytopic carboranyl-terminated (semi)clathrochelate metal complexes, based on the template synthesis, transmetallation, amide condensation and 1,3-dipolar cycloaddition reactions, is developed.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00076A

Reference85 articles.

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2. Y.Voloshin , I.Belaya and R.Kramer , Cage Metal Complexes: Clathrochelates Revisited , Springer , 2017

3. Anionic Bipyridyl Ligands for Applications in Metallasupramolecular Chemistry

4. Dinuclear clathrochelate complexes with pendent cyano groups as metalloligands

5. Carboxylic Acid Functionalized Clathrochelate Complexes: Large, Robust, and Easy-to-Access Metalloligands

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