Cu-loaded zeolites enable the selective activation of ethane to ethylene at low temperatures and pressure-Reference-Cited by-同舟云学术

Cu-loaded zeolites enable the selective activation of ethane to ethylene at low temperatures and pressure

Published:2023 Issue:40 Volume:59 Page:6052-6055
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kvande Karoline¹^ORCID,Prodinger Sebastian¹,Solemsli Bjørn Gading¹,Bordiga Silvia²^ORCID,Borfecchia Elisa²^ORCID,Olsbye Unni¹^ORCID,Beato Pablo³^ORCID,Svelle Stian¹^ORCID

Affiliation:

1. Centre for Materials Science and Nanotechnology (SMN), Department of Chemistry, University of Oslo, 1033 Blindern, 0315, Oslo, Norway

2. Department of Chemistry, NIS Center and INSTM Reference Center, University of Turin, via P. Giuria 7, 10125 Turin, Italy

3. Topsoe A/S, Haldor Topsøes Alle 1, DK-2800 Kgs, Lyngby, Denmark

Abstract

Sending ethane over Cu-oxo sites in zeolites allows for the selective formation of ethylene in a stepwise reaction at mild conditions. Experimental results indicate that the reaction proceeds via the formation of ethanol intermediates.

Funder

Norges Forskningsråd

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC00948C

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4. Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol

5. Selective Oxidation of Methane by the Bis(μ-oxo)dicopper Core Stabilized on ZSM-5 and Mordenite Zeolites

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