P–C reductive elimination in Ru(ii) complexes to convert triarylphosphine ligands into five- or six-membered phosphacycles-Reference-Cited by-同舟云学术

P–C reductive elimination in Ru(ii) complexes to convert triarylphosphine ligands into five- or six-membered phosphacycles

Published:2018 Issue:42 Volume:54 Page:5357-5360
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kuwabara Takuya¹²³⁴⁵^ORCID,Kato Takahiro¹²³⁴⁵,Takano Kouichi¹²³⁴⁵,Kodama Shintaro¹²³⁴⁵,Manabe Yuuka⁶⁷⁸⁹¹⁰,Tsuchida Noriko⁶⁷⁸⁹¹⁰,Takano Keiko⁶⁷⁸⁹¹⁰,Minami Yasunori¹¹²⁴⁵,Hiyama Tamejiro¹¹²⁴⁵^ORCID,Ishii Youichi¹²³⁴⁵^ORCID

Affiliation:

1. Department of Applied Chemistry, Faculty of Science and Engineering

2. Chuo University

3. 1-13-27 Kasuga

4. Tokyo 112-8551

5. Japan

6. Department of Chemistry and Biochemistry

7. Graduate School of Humanities and Sciences

8. Ochanomizu University

9. Otsuka

10. Tokyo 112-8610

11. Research and Development Initiative

Abstract

η⁴-Phosphacycle complexes were obtained from PPh₂Ar (Ar = Ph, 1-Naph) via cyclometallation, alkyne insertion and P–C reductive elimination at a Ru centre.

Funder

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC02539H

Reference52 articles.

1. Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds

2. CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

3. Palladium-Catalyzed Transformations of Alkyl C–H Bonds

4. Transition metal-mediated P–C/X exchange at bound phosphine ligands (X = aryl, alkyl, NR2, OR and F): scope and mechanisms

5. Facile aryl-aryl exchange between the palladium center and phosphine ligands in palladium(II) complexes

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