Highly selective one-step hydrogenation of nitrobenzene to cyclohexylamine over the supported 10% Ni/carbon catalysts doped with 3‰ Rh-Reference-Cited by-同舟云学术

Highly selective one-step hydrogenation of nitrobenzene to cyclohexylamine over the supported 10% Ni/carbon catalysts doped with 3‰ Rh

Published:2016 Issue:19 Volume:6 Page:15354-15361
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Lu Xinhuan¹²³⁴⁵,chen Yang¹²³⁴⁶,Zhao Zhenshuang¹²³⁴⁶,Deng Hao¹²³⁴⁶,Zhou Dan¹²³⁴⁶,Wei Changcheng¹²³⁴⁶,Nie Renfeng¹²³⁴⁶,Xia Qinghua¹²³⁴⁶

Affiliation:

1. Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials

2. Hubei University

3. Wuhan 430062

4. P. R. China

5. Hubei Key Laboratory for Processing and Application of Catalytic Materials

6. Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules

Abstract

The catalyst 3‰ Rh–10% Ni/CSC exhibits an excellent performance to achieve 100 mol% conversion of nitrobenzene and 91.6% selectivity of fully-hydrogenated cyclohexylamine under conditions of 3.5 MPa H₂ and 140 °C.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA27202E

Reference55 articles.

1. Aromatic saturation of distillates: an overview

2. Naphthalene Hydrogenation over Pt/Al2O3 Catalyst in a Trickle Bed Reactor

3. Reactions of Tetralin with Tritiated Molecular Hydrogen on Pt/Al2O3, Pd/Al2O3, and Pt−Pd/Al2O3 Catalysts

4. A Novel Transfer Hydrogenation with High Hydrogen Utilization for the Hydrogenation of Halogenated Nitrobenzene without Hydrodehalogenation

5. A green synthesis route of ortho-chloroaniline: Solvent-free selective hydrogenation of ortho-chloronitrobenzene over Pt–Ru/Fe3O4/C catalyst

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