Synthesis of discrete Re(i) di- and tricarbonyl assemblies using a [4 × 1] directional bonding strategy
Author:
Affiliation:
1. Départment de Chimie
2. Université de Montréal
3. Montréal
4. Canada
Abstract
Discrete assembly of two Re(i) squares was achieved by a simple [4 × 1] strategy where the complexes, [Re(4-pytpy-κ2N)(CO)3Br] and [Re(4-pytpy-κ3N)(CO)2Br], act as their own ligands. The properties of the assemblies and their precursors are described along with solid-state X-ray diffraction studies.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03077J
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