Cluster transformation of [Cu3(μ3-H)(μ3-BH4)((PPh2)2NH)3](BF4) to [Cu3(μ3-H)(μ2,μ1-S2CH)((PPh2)2NH)3](BF4) via reaction with CS2. X-ray structural characterisation and reactivity of cationic clusters explored by multistage mass spectrometry and computational studies
Author:
Affiliation:
1. School of Chemistry and Bio21 Molecular Science and Biotechnology Institute
2. University of Melbourne
3. Parkville
4. Australia
5. School of Physical Sciences
6. University of Tasmania
7. Hobart
Abstract
[Cu3(μ3-H)(μ3-BH4)((PPh2)2NH)3](BF4) reacts with CS2 to produce [Cu3(μ3-H)(μ2,μ1-S2CH)((PPh2)2NH)3](BF4), whose cation loses CH2S upon ligand loss.
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03510A
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