Wavelength dependent photoextrusion and tandem photo-extrusion reactions of ninhydrin bis-acetals for the synthesis of 8-ring lactones, benzocyclobutenes and orthoanhydrides

Author:

Sun Wei1,Kayal Surajit2ORCID,Raimbach William A. T.1,Sun Xue-Zhong2,Light Mark E.1,Hanson-Heine Magnus W. D.2ORCID,George Michael W.23ORCID,Harrowven David C.1ORCID

Affiliation:

1. Chemistry, University of Southampton, Highfield, Southampton, SO17 1BJ, UK

2. School of Chemistry, University of Nottingham, Nottingham NG7 2RD, UK

3. Department of Chemical and Environmental Engineering, University of Nottingham Ningbo China, 199 Taikang East Road, Ningbo 315100, China

Abstract

Ninhydrin bis-acetals give access to 8-ring lactones, benzocyclobutenes and spirocyclic orthoanhydrides through photoextrusion and tandem photoextrusion reactions.

Funder

European Regional Development Fund

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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