Generic synthesis of high-entropy phosphides for fast and stable Li-ion storage

Author:

Li Wenwu1,Li Yanhong1,Wang Jeng-Han2,Huang Shengchi2,Chen Anjie2,Yang Lufeng34,Chen Jie34,He Lunhua45ORCID,Pang Wei Kong6ORCID,Thomsen Lar7,Cowie Bruce7,Xiong Peixun1ORCID,Zhou Yucun8,Jang Gun1,Min Dong Hyun1,Byun Jin Suk1,Xu Lei910,Huang Jia-Qi910ORCID,Roh Kwang Chul11ORCID,Kang Seo Hui1112ORCID,Liu Meilin8ORCID,Duan Xiangfeng13ORCID,Park Ho Seok1141516ORCID

Affiliation:

1. School of Chemical Engineering, Sungkyunkwan University, 2066, Seoburo, Jangan-gu, Suwon 440-746, Republic of Korea

2. Department of Chemistry, National Taiwan Normal University, Taipei, 11677, Taiwan

3. Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, China

4. Spallation Neutron Source Science Center, Dongguan, China

5. Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing, China

6. Institute for Superconducting & Electronic Materials, University of Wollongong, Wollongong, NSW, Australia

7. Australian Synchrotron, Australian Nuclear Science and Technology Organization, Clayton Victoria 3168, Australia

8. School of Materials Science & Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA

9. School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China

10. Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China

11. Energy Storage Materials Center, Korea Institute of Ceramic Engineering and Technology, Jinju-Si, Gyeongsangnam-do 52851, Republic of Korea

12. Department of Materials Science and Engineering, Korea University, Anam-Dong, Seongbuk-Gu, Seoul 136-713, Republic of Korea

13. Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095, USA

14. Department of Health Sciences and Technology, Samsung Advanced Institute for Health Sciences and Technology (SAIHST), Sungkyunkwan University, 2066, Seoburo, Jangan-gu, Suwon, 440-746, Republic of Korea

15. SKKU Advanced Institute of Nano Technology (SAINT), Sungkyunkwan University, 2066, Seoburo, Jangan-gu, Suwon, 440-746, Republic of Korea

16. SKKU Institute of Energy Science and Technology (SIEST), Sungkyunkwan University, 2066, Seoburo, Jangan-gu, Suwon 440-746, Republic of Korea

Abstract

High-entropy phosphides are first synthesized, achieving much faster charge transfer and greater anti-pulverization capability than the parent phases owing to the high configurational entropy.

Funder

National Research Foundation of Korea

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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