N-Heterocyclic carbene-based porous polymer macroligand for the Ni-catalyzed C–H arylation of benzothiophenes-Reference-Cited by-同舟云学术

N-Heterocyclic carbene-based porous polymer macroligand for the Ni-catalyzed C–H arylation of benzothiophenes

Published:2023 Issue:20 Volume:13 Page:5825-5830
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Samanta Partha¹^ORCID,Beucher Remi¹,Kumari Riddhi Riddhi¹^ORCID,Ranscht Alisa¹,Wisser Florian M.²^ORCID,Quadrelli Elsje Alessandra¹^ORCID,Canivet Jerome¹^ORCID

Affiliation:

1. Univ. Lyon, Université Claude Bernard Lyon 1, CNRS, IRCELYON – UMR 5256, 2 Av. Albert Einstein, 69626 Villeurbanne Cedex, France

2. Erlangen Center for Interface Research and Catalysis, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen, Germany

Abstract

A novel single-site Ni(NHC) catalyst embedded within a porous polymer has been developed for the heterogeneous direct C–H arylation of (benzo)thiophenes with unprecedented stability and recyclability.

Funder

Agence Nationale de la Recherche

Horizon 2020 Framework Programme

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D3CY01263H

Reference48 articles.

1. Why Does Industry Not Use Immobilized Transition Metal Complexes as Catalysts?

2. Porous Macroligands: Materials for Heterogeneous Molecular Catalysis

3. Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure

4. Single sites in heterogeneous catalysts: separating myth from reality

5. Hammett Parameter in Microporous Solids as Macroligands for Heterogenized Photocatalysts

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