Copolymerization of cyclic esters, epoxides and anhydrides: evidence of the dual role of the monomers in the reaction mixture-Reference-Cited by-同舟云学术

Copolymerization of cyclic esters, epoxides and anhydrides: evidence of the dual role of the monomers in the reaction mixture

Published:2018 Issue:19 Volume:8 Page:5034-5043
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Isnard Florence¹²³⁴,Carratù Mario¹²³⁴,Lamberti Marina⁵²⁶⁴^ORCID,Venditto Vincenzo¹²³⁴^ORCID,Mazzeo Mina¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biology “A. Zambelli”

2. University of Salerno

3. 84084 Fisciano (SA)

4. Italy

5. Department of Physics “E. Caianiello”

6. 132 84084 Fisciano (SA)

Abstract

A block copolyester derived from ROCOP of CHO/SA followed by ROP of ε-CL was obtained from the mixture of monomers. The lactone comonomer acts as an endogen cocatalyst during the SA/CHO ROCOP step and as a monomer during ROP.

Funder

Fondazione Cariplo

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C8CY01174E

Reference75 articles.

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