Heavy pnicogen atoms as electron donors in sigma-hole bonds

Author:

Amonov Akhtam1,Scheiner Steve2ORCID

Affiliation:

1. Department of Optics and Spectroscopy Engineering Physics Institute, Samarkand State University, University blv. 15, Samarkand 140104, Uzbekistan

2. Department of Chemistry and Biochemistry, Utah State University Logan, Utah 84322-0300, USA

Abstract

DFT calculations evaluate the strength of σ-hole bonds formed by ZH3and ZMe3(Z = N, P, As, Sb) acting as electron donor.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference90 articles.

1. G. C.Pimentel and A. L.McClellan , The Hydrogen Bond , Freeman , San Francisco , 1960

2. W. C.Hamilton and J. A.Ibers , Hydrogen Bonding in Solids , W. A. Benjamin , New York , 1968

3. M. D.Joesten and L. J.Schaad , Hydrogen Bonding , Marcel Dekker , New York , 1974

4. Hydrogen Bonding and Proton Transfer in the Ground and Lowest Excited Singlet States of o-Hydroxyacetophenone

5. P.Schuster , G.Zundel and C.Sandorfy , The Hydrogen Bond. Recent Developments in Theory and Experiments , North-Holland Publishing Co. , Amsterdam , 1976

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