A new hexanuclear Fe(iii) nanocluster: synthesis, structure, magnetic properties, and efficient activity as a precatalyst in water oxidation

Author:

Akhtar Muhammad Nadeem1ORCID,Bikas Rahman2ORCID,AlDamen Murad A.3ORCID,Shaghaghi Zohreh4ORCID,Shahid M.5ORCID,Sokolov Andrei6

Affiliation:

1. Division of Inorganic Chemistry, Institute of Chemistry, The Islamia University of Bahawalpur, Bahawalpur, 63100, Pakistan

2. Department of Chemistry, Faculty of Science, Imam Khomeini International University, 34148-96818 Qazvin, Iran

3. Department of Chemistry, School of Science, the University of Jordan, Amman 11942, Jordan

4. Coordination Chemistry Research Laboratory, Department of Chemistry, Faculty of Basic Science, Azarbaijan Shahid Madani University, 5375171379, Tabriz, Iran

5. Functional Inorganic Materials Lab (FIML), Department of Chemistry, Aligarh Muslim University, Aligarh 202002, India

6. Department of Physics and Astronomy, University of Nebraska-Lincoln, Lincoln, NE 68588, USA

Abstract

The oxo-bridged hexanuclear iron coordination cluster and its magnetic and electrocatalytic activity for water oxidation are presented. Experiments confirm that the electrode modified by this cluster is active for water oxidation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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