Kinetically labile ruthenium(ii) complexes of terpyridines and saccharin: effect of substituents on photoactivity, solvation kinetics, and photocytotoxicity

Author:

Kumar Priyaranjan1234ORCID,Singh Prerana56234,Saren Sanjoy1234,Pakira Sandip1234,Sivakumar Sri56234ORCID,Patra Ashis K.1234ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Kanpur

3. Kanpur 208016

4. India

5. Department of Chemical Engineering

6. DST Thematic Unit of Excellence on Soft Nanofabrication

Abstract

A series of kinetically labile [RuII(R-tpy)(sac)2X] complexes explored for structure, solvation, DNA and BSA binding, photoactivity, ROS generation and apoptosis assessment.

Funder

Indian Council of Medical Research

Science and Engineering Research Board

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference96 articles.

1. E. A. Seddon and K. R.Seddon , The Chemistry of Ruthenium , Elsevier Science Publication BV , Amsterdam , 1984

2. Ruthenium-Catalyzed Reactions for Organic Synthesis

3. Metal-Ligand Exchange Kinetics in Platinum and Ruthenium Complexes

4. S. Campagna , F.Puntoriero , F.Nastasi , G.Bergamini and V.Balzani , Photochemistry and Photophysics of Coordination Compounds: Ruthenium , ed. V. Balzani and S. Campagna , Springer , Berlin, Heidelberg , 2007 , vol. 280 , pp. 117–214

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