Electrosynthesis ofN,N-dimethylformamide from market-surplus trimethylamine coupled with hydrogen production

Author:

Jin Meng1,Li An-Zhen1,Wang Ye1,Li Jing1,Zhou Hua2,Li Bi-Jie1ORCID,Duan Haohong13ORCID

Affiliation:

1. Department of Chemistry, Tsinghua University, Beijing 100084, China

2. State Key Laboratory of Chemical Resource Engineering, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China

3. Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China

Abstract

We report an electrochemical oxidation strategy to synthesize DMF directly from market-surplus trimethylamine and couple it with hydrogen production. The reaction was achieved in an aqueous medium without any mediator using water as the oxidant.

Funder

Natural Science Foundation of Beijing Municipality

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference56 articles.

1. G.Bellussi , M.Bohnet , J.Bus , K.Drauz , H.Greim , K.-P.Jackel , T.Laird , U.Kars , A.Kleemann , G.Kreysa , W.Meier , E.Otto , M.Roper , J.Scholtz , K.Sundmacher , R.Ulber and U.Wietelmann , Formamides , in Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH , Weinheim , 2011

2. K.Weissermel and H.-J.Arpe , Industrial Organic Chemistry , ed. C. R.Lindley and S.Hawkins , Wiley-VCH , Weinheim , 4th edn, 2003 , pp. 44–46

3. N,N-Dimethylformamide: A Multipurpose Building Block

4. N,N-Dimethylformamide: much more than a solvent

5. Dimethylformamide (DMF) Market by Type (Reactant and Feedstock), End-use industries (Chemicals, Electronics, Pharmaceutical, and Agrochemical), and Region (Asia Pacific, Europe, North America, Europe, MEA and South America) - Global Forecast to 2027 (Market Research Report, MarketsandMarkets, 2021). https://www.marketsandmarkets.com/Market-Reports/dimethylformamide-market-129340374.html

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