Asymmetric addition of hydrazones as alkyl carbanion equivalents with aryl imines in water-Reference-Cited by-同舟云学术

Asymmetric addition of hydrazones as alkyl carbanion equivalents with aryl imines in water

Published:2023 Issue:12 Volume:10 Page:3021-3026
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Wang Yi-Zhan¹²^ORCID,Liu Shao-Dong¹²^ORCID,Cheng Liang¹²^ORCID,Liu Li¹²^ORCID,Li Chao-Jun³^ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

2. University of Chinese Academy of Sciences, Beijing 100049, China

3. Department of Chemistry and FRQNT Center for Green Chemistry and Catalysis, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 0B8, Canada

Abstract

An asymmetric umpolung addition of hydrazones as alkyl carbanion equivalents with imines in water was developed under the catalysis of a chiral Ru–diamine–diphosphine system.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00475A

Reference51 articles.

1. Direct catalytic asymmetric synthesis of α-chiral primary amines