Reversing Mg suppression effect on Co-site water oxidation of MgCo2O4 based on vanadium-atom electronic affinity synergy with Mg sites toward electronic redistribution

Author:

Zhang Hui1,Han Hui1,Yang Xuan1,Ma Hongyu1,Song Zhifei12,Ji Xuqiang1ORCID

Affiliation:

1. College of Materials Science and Engineering, Institute for Graphene Applied Technology Innovation, Qingdao University, Qingdao 266071, Shandong, China

2. School of Electromechanic Engineering, Qingdao University, Qingdao 266071, China

Abstract

Vanadium-doping-tailored MgCo2O4 coupled with MgO (V–MgCo2O4@MgO) exhibits significantly reinforced OER performance, with low overpotentials of 240 and 290 mV for 100 and 500 mA cm−2, respectively, in 1 M KOH.

Funder

Natural Science Foundation of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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