Rate constants and kinetic isotope effects for H-atom abstraction reactions by muonium in the Mu + propane and Mu + n-butane reactions from 300 K to 435 K: challenges for theory
Author:
Affiliation:
1. TRIUMF and Department of Chemistry
2. University of British Columbia
3. Vancouver
4. Canada
5. TRIUMF
6. ISIS Facility
7. STFC Rutherford Appleton Laboratory
8. Didcot
9. UK
Abstract
This paper reports measurements of the temperature dependence of the rate constants for H-atom abstraction reactions from propane and n-butane by the light isotopic H-atom muonium (Mu), kMu(T), over temperatures in the range 300 K to 435 K.
Funder
Natural Sciences and Engineering Research Council of Canada
Seventh Framework Programme
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP06822H
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4. Zero-point energy, tunnelling, and vibrational adiabaticity in the Mu + H2reaction
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