Tellurolate: an effective Te-atom transfer reagent to prepare the triad of group 5 metal bis(tellurides)-Reference-Cited by-同舟云学术

Tellurolate: an effective Te-atom transfer reagent to prepare the triad of group 5 metal bis(tellurides)

Published:2023 Issue:43 Volume:14 Page:12277-12282
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Senthil Shuruthi¹,Kwon Seongyeon²³,Kong Richard Y.⁴^ORCID,MacMillan Samantha N.⁴^ORCID,Zatsepin Pavel¹^ORCID,Gau Michael R.¹,Carroll Patrick J.¹,Baik Mu-Hyun³²^ORCID,Lancaster Kyle M.⁴^ORCID,Mindiola Daniel J.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104, USA

2. Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea

3. Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Republic of Korea

4. Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, USA

Abstract

We show in this work how lithium tellurolate Li(X)nTeCH2SiMe3 (X = THF, n = 1, 1; X = 12-crown-4, n = 2, 2), can serve as an effective Te-atom transfer reagent to all group 5 transition metal halide precursors irrespective of their oxidation state.

Funder

Cornell University

University of Pennsylvania

National Science Foundation

U.S. Department of Energy

Basic Energy Sciences

National Institutes of Health

National Institute of General Medical Sciences

Institute for Basic Science

Publisher

Royal Society of Chemistry (RSC)

Subject