Synthesis and X-ray crystal structure of the dimolybdenum acetaldehyde complex [Mo2(η-MeCHO)(CO)4(η-C5H5)2]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1991/DT/DT9910002217
Reference39 articles.
1. Alkyl and aryl derivatives of π-cyclopentadienyl compounds of chromium, molybdenum, tungsten, and iron
2. Reactions of hydride reagents with alkylmolybdenum carbonyl complexes. Reaction of LiBHEt3with [MoMe(CO)3(η-C5H5)], formation of an anionic acetaldehyde complex, and a stoicheiometric cycle for the synthesis of acetaldehyde
3. The reaction of MoMe(CO)3(η-C5H5) with LiEt3BH, formation of an anionic η2-acetaldehyde–molybdenum complex via formyl alkyl and hydrido acyl molybdenum intermediates
4. Acetaldehyde complexes of molybdenum
5. Formation of the alkoxyalkyl complexes [M{CHMe(OMe)}(CO)2(η-C5H4R)](M = Mo, R = H; M = W, R = H or Me) and their transformations by loss of MeOH into η3-propenoyl or vinyl complexes. Crystal structures of [Mo{CHMe(PPh3)}(CO)2(PPh3)(η-C5H5)]BF4, [Mo(η3-CH2CHCO)(CO)(PPh3)(η-C5H5)] and [W(σ-CHCH2)(CO)2(PPh3)(η-C5H4Me)]
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2. Rhenium(I) Terpyridine π-Bases: Reversible η2-Coordination of Ketones, Aldehydes, and Olefins in the Terpyridine Plane;Organometallics;1999-01-22
3. Hydride transfer reactions of transition metal hydrides in the preparation of [Cp(CO)3W(η1-aldehyde)]+OTf− and [Cp(CO)3W(η1-ketone)]+OTf− complexes;Inorganica Chimica Acta;1997-06
4. Electrophilic Attack on the Carbon Terminus of a Niobium-Bound Formaldehyde Ligand;Organometallics;1997-03-01
5. Cycloheptatriene and -enyl Complexes of the Early Transition Metals;Chemical Reviews;1995-03
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