Convenient syntheses of the square-bipyramidal cluster, [Co4(µ-4-GeMe)2(CO)11] and the formation of [Co4(µ4-GeMe)-{µ4-GeCo(CO)4}(CO)11] and [Co4{µ4-GeMn(CO)5}-{µ4-GeCo(CO)4}(CO)11]: new Ge2Co4clusters containing the square-bipyramidal skeleton; and the crystal structure of [Co4(µ4-GeMe){µ4-GeCo(CO)4}(CO)11]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1991/DT/DT9910001209
Reference36 articles.
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2. Aufbau Germylidin‐verbrückter Drei‐ und Vierkerncluster
3. Darstellung und metallaustausch der cluster (RGe)2Co4(CO)11
4. Transition-metal carbonyl derivatives of the germanes. 15. Reaction of digermane and related species with cobalt carbonyl: formation of Ge2Co6(CO)20 and its conversion to a closed cluster [.mu.4-GeCo(CO)4]2Co4(CO)11
5. [μ4-SiCo(CO)4]2Co4(CO)11, a cobalt carbonyl cluster incorporating five-coordinate silicon
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