Effect of the cation size on the framework structures of magnesium tungstate, A4Mg(WO4)3 (A = Na, K), R2Mg2(WO4)3 (R = Rb, Cs)

Author:

Han Shujuan123,Wang Ying12345,Jing Qun12345,Wu Hongping123,Pan Shilie123,Yang Zhihua123

Affiliation:

1. Key Laboratory of Functional Materials and Devices for Special Environments of CAS; Xinjiang Key Laboratory of Electronic Information Materials and Devices; Xinjiang Technical Institute of Physics & Chemistry of CAS

2. Urumqi 830011

3. China

4. University of Chinese Academy of Sciences

5. Beijing 100049

Abstract

A series of alkali metal magnesium tungstates, A4Mg(WO4)3 (A = Na, K), R2Mg2(WO4)3 (R = Rb, Cs), were synthesized from a high temperature solution, and their structures were determined by single-crystal X-ray diffraction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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