Cyclic trimers of phosphinic acids in polar aprotic solvent: symmetry, chirality and H/D isotope effects on NMR chemical shifts
Author:
Affiliation:
1. Institute of Chemistry
2. St. Petersburg State University
3. Russia
4. Department of Physics
5. Faculty of Chemistry and Pharmacy
6. University of Regensburg
7. Germany
Abstract
By using NMR in liquefied gases, the stoichiometry of hydrogen-bonded complexes is determined via H/D isotope effects on proton chemical shifts.
Funder
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP08130H
Reference45 articles.
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2. Particular features of the ν(OH) absorption band of strongly hydrogen-bonded complexes in the gas phase, low-temperature matrices, and crystalline films at 12–600 K
3. Dynamic NMR Study of the Mechanisms of Double, Triple, and Quadruple Proton and Deuteron Transfer in Cyclic Hydrogen Bonded Solids of Pyrazole Derivatives
4. Infrared and ab initio studies of hydrogen bonding and proton transfer in the complexes formed by pyrazoles
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