NHC/B(OH)<sub>3</sub>-mediated C3-selective acylation of unprotected monosaccharides: mechanistic insights and toward simpler/greener solutions-Reference-Cited by-同舟云学术

NHC/B(OH)₃-mediated C3-selective acylation of unprotected monosaccharides: mechanistic insights and toward simpler/greener solutions

Published:2024 Issue:10 Volume:26 Page:5997-6004
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Jin Jiamiao¹²,Guo Jiangtao²³,Xu Feng²³,Lv Ya¹,Wang Guanjie²,Song Jia¹,Lv Wen-Xin¹^ORCID,Li Tingting¹^ORCID,Chi Yonggui Robin¹²^ORCID

Affiliation:

1. State Key Laboratory of Green Pesticides, Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Center for R&D of Fine Chemicals of Guizhou University, Guiyang, 550025, China

2. School of Chemistry, Chemical Engineering, and Biotechnology, Nanyang Technological University, Singapore, 637371, Singapore

3. School of Medicine, Guizhou University of Traditional Chinese Medicine, Guiyang, China

Abstract

A simple and greener protocol for the regio-selective acylation of unprotected monosaccharides is achieved using boric acid as a promoter and N-heterocyclic carbene as an organic catalyst.

Funder

National Basic Research Program of China

Department of Education of Guizhou Province

Natural Science Foundation of Guizhou Province

Higher Education Discipline Innovation Project

Guizhou University

National Research Foundation Singapore

Ministry of Education - Singapore

Nanyang Technological University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)