Hydrolysis of amide bonds in dipeptides and nylon 6 over a ZrO<sub>2</sub> catalyst-Reference-Cited by-同舟云学术

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Hydrolysis of amide bonds in dipeptides and nylon 6 over a ZrO₂ catalyst

Published:2024 Issue:14 Volume:14 Page:3898-3908
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Tomita Satoshi¹,Yabushita Mizuho¹^ORCID,Nakagawa Yoshinao¹^ORCID,Tomishige Keiichi¹²^ORCID

Affiliation:

1. Department of Applied Chemistry, School of Engineering, Tohoku University, 6-6-07 Aoba, Aramaki, Aoba-ku, Sendai, Miyagi 980-8579, Japan

2. Advanced Institute for Materials Research (WPI-AIMR), Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577, Japan

Abstract

The amphoteric ZrO2 surface catalyzed the hydrolysis of various amide compounds: dipeptides into amino acids; small organic amides into the equimolar amount of carboxylic acids and amines; and nylon 6 into ε-caprolactam and ε-aminocaproic acid.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CY/D4CY00533C

Reference42 articles.

1. Amide bond formation and peptide coupling

2. Rethinking amide bond synthesis

3. Catalytic Cleavage of Amide C−N Bond: Scandium, Manganese, and Zinc Catalysts for Esterification of Amides

4. Chemical Recycling Processes of Nylon 6 to Caprolactam: Review and Techno-Economic Assessment

5. A sustainable way of recycling polyamides: dissolution and ammonolysis of polyamides to diamines and diamides using ammonia and biosourced glycerol

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