Highly functionalizable penta-coordinate iron hydrogen production catalysts with low overpotentials
Author:
Affiliation:
1. Department of Chemistry
2. University of Michigan
3. 930 North University Ave
4. Ann Arbor
5. USA
6. Department of Chemical Engineering
Abstract
Penta-coordinate iron complexes with ‘PNP’ diphosphine ligands, [Fe(S2C6H4)((C6H5)2PN(R)P(C6H5)2)CO], all air-stable FeII compounds, show electrocatalytic H2 production at low overpotentials (η = 0.09–0.21 V vs. Pt). These catalysts utilize an EC mechanism, where one-electron reduction triggers protonation by weak acids.
Funder
National Science Foundation
3M
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03744A
Reference60 articles.
1. Sustainable Hydrogen Production
2. R. Cammack , M.Frey and R.Robson, Hydrogen as a Fuel: Learning from Nature, Taylor & Francis, London and New York, 2001
3. Steps toward the hydrogen economy
4. Earth-abundant hydrogen evolution electrocatalysts
5. Recent progress in electrochemical hydrogen production with earth-abundant metal complexes as catalysts
Cited by 15 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Structural Features of Complexes [Co(dppaPh)2(CH3CN)2](BF4)2 and [Co(dppaPh)2(η1-P4)]BF4 (dppaPh = N,N-bis(Diphenylphosphino)Aniline);Journal of Structural Chemistry;2023-05
2. Bulky oxadithiolate-bridged [FeFe]‑hydrogenase mimics [Fe2(μ-R2odt)(CO)4(κ-diphosphine)] (R = Ph and H) with chelating diphosphines;Journal of Inorganic Biochemistry;2022-10
3. Preparation of Dicarbonyl Iron Compounds with a Bidentate Phosphine and Their CO Release Behaviors upon Irradiation;CHINESE J INORG CHEM;2022
4. Investigations on the PNP‐chelated diiron dithiolato complexes Fe 2 (μ‐edt)(CO) 4 {κ 2 ‐(Ph 2 P) 2 NC 6 H 4 R} related to the [FeFe]‐hydrogenase active site;Zeitschrift für anorganische und allgemeine Chemie;2021-01-29
5. Electrochemical behaviors of a pincer-type NNN-Fe complex and catalytic H2 evolution activity;Chemical Communications;2021
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3