A 2D flexible cobalt-MOF: reversible solid-state structural transformation, two-step and gate-opening adsorption behaviours, and selective adsorption of C2H2over CO2and CH4

Author:

Wang Shan-Shan1,Liang Yu-Jie1,Guo Wei1,Yin Yue1,Li Xiao-Yu1,Xu Quan-Qing1,Zhu Ai-Xin1ORCID,Huang Bo1

Affiliation:

1. Faculty of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500, China

Abstract

A 2D cobalt(ii) framework exhibits reversible solid-state structural transformations, gas-induced, two-step and type F-IV adsorption isotherms at 195 K as well as selective C2H2adsorption over CO2and CH4at 298 K.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference60 articles.

1. L. R.MacGillivray , Metal–organic frameworks: Design and application , John Wiley & Sons , 2010

2. Functional Porous Coordination Polymers

3. S. R.Batten , S. M.Neville and D. R.Turner , Coordination polymers: design, analysis and application Introduction , Royal Society of Chemistry , London , 2009

4. Soft porous crystals

5. Flexible metal–organic frameworks

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