Mechanistic insights into Smiles rearrangement. Focus on π–π stacking interactions along the radical cascade
Author:
Affiliation:
1. Institut de Chimie Moléculaire de Reims UMR CNRS 7312
2. Université de Reims Champagne-Ardenne
3. Reims Cedex 02 BP39
4. France
Abstract
The synthesis of new arene and heteroarene scaffolds of therapeutic interest has generated a renewed interest in the domino radical cyclisation–Smiles.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01511C
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1. Ynamide Smiles Rearrangement Triggered by Visible-Light-Mediated Regioselective Ketyl–Ynamide Coupling: Rapid Access to Functionalized Indoles and Isoquinolines
2. Modern Aspects of the Smiles Rearrangement
3. A novel 1,4 arylradical rearrangement.
4. Intramolecular radical reactions in α-halomethyl substituted piperidine sulfonamides by
5. A truce on the Smiles rearrangement: revisiting an old reaction—the Truce–Smiles rearrangement
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