Coordination vs. oxidative rearrangement of photochromic spiropyrans upon reacting with FeIIICl3 and FeIIIBr3-Reference-Cited by-同舟云学术

Coordination vs. oxidative rearrangement of photochromic spiropyrans upon reacting with Fe^IIICl₃ and Fe^IIIBr₃

Published:2024 Issue:30 Volume:48 Page:13526-13537
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Osipov Nikita G.¹^ORCID,Faraonov Maxim A.¹^ORCID,Kuzmin Alexey V.²,Khasanov Salavat S.²,Shestakov Alexander F.¹³,Denisov Nikolay N.¹^ORCID,Savinykh Tatiana A.¹^ORCID,Otsuka Akihiro⁴^ORCID,Kitagawa Hiroshi⁴^ORCID,Konarev Dmitri V.¹^ORCID

Affiliation:

1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS, Chernogolovka, Moscow region, 142432, Russia

2. Institute of Solid State Physics RAS, Chernogolovka, Moscow region, 142432, Russia

3. Department of Fundamental Physical and Chemical Engineering, M.V. Lomonosov Moscow State University, 119991, Moscow, Russia

4. Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan

Abstract

Photochromic spiropyrans form complexes with FeIIICl3 or FeIIIBr3. They have intense absorption in the visible range. Planar TMNOY+ cations (shown on the right) were also obtained by the oxidation and deprotonation of spiropyran with FeIIIBr3.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ02371D

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