First GC/MS identification of aqueous ammonia: utilization of ethenesulfonyl fluoride as a selective and rapid derivatization reagent of ammonia in aqueous media

Author:

Shiraki Ryosuke12ORCID,Wakigawa Kengo2,Ogawa Shin2,Gohda Akinaga2,Mori Takeshi134ORCID,Katayama Yoshiki13456ORCID

Affiliation:

1. Graduate School of Systems Life Sciences, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

2. Forensic Science Laboratory, Fukuoka Prefectural Police Headquarters, 7-7 Higashikoen, Hakata-ku, Fukuoka 812-8576, Japan

3. Department of Applied Chemistry, Faculty of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

4. Center for Future Chemistry, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

5. International Research Center for Molecular Systems, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

6. Center for Advanced Medical Innovation, Kyushu University, 3-1-1 Maidashi, Higashi-ku, Fukuoka 812-8532, Japan

Abstract

Ethenesulfonyl fluoride was used as a derivatization reagent for aqueous ammonia in GC/MS identification. This method was tolerable to some amine-containing interfering substances and applicable to ammonia quantification of commercial products.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Chemical Engineering,Analytical Chemistry

Reference32 articles.

1. P.Warneck , Chemistry of the Natural Atmosphere , Academic Press , 2nd edn, 2000

2. Ammonia in the atmosphere: a review on emission sources, atmospheric chemistry and deposition on terrestrial bodies

3. Corrosion of hot‐dip‐galvanised steel and zinc alloy‐coated steel in ammonia and ammonium chloride

4. World Health Organization , Environmental Health Criteria 54 , 1986 , https://inchem.org/

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