Functionalised polyhedral oligomeric silsesquioxane with encapsulated fluoride – first observation of fluxional Si⋯F interactions in POSS-Reference-Cited by-同舟云学术

Functionalised polyhedral oligomeric silsesquioxane with encapsulated fluoride – first observation of fluxional Si⋯F interactions in POSS

Published:2021 Issue:1 Volume:50 Page:81-89
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Laird Mathilde¹²³⁴⁵^ORCID,Totée Cédric¹²³⁴⁵,Gaveau Philippe¹²³⁴⁵,Silly Gilles¹²³⁴⁵,Van der Lee Arie⁶⁷²³⁴^ORCID,Carcel Carole¹²³⁴⁵^ORCID,Unno Masafumi⁸⁹¹⁰¹¹^ORCID,Bartlett John R.¹²¹³¹⁴^ORCID,Wong Chi Man Michel¹²³⁴⁵^ORCID

Affiliation:

1. ICGM Univ. Montpellier

2. CNRS

3. ENSCM

4. Montpellier

5. France

6. Institut Européen des Membranes

7. Univ. Montpellier

8. Department of Chemistry and Chemical Biology

9. Graduate School of Science and Technology

10. Gunma University

11. Japan

12. Western Sydney University

13. Penrith

14. Australia

Abstract

The first observation of fluxional covalent Si⋯F interactions in functionalised T₈-F cage silsesquioxanes containing an encapsulated fluoride is reported.

Funder

Ministère de l'Enseignement Supérieur et de la Recherche

Japan Student Services Organization

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT03057K

Reference38 articles.

1. Cage-like silsesquioxanes-based hybrid materials

2. Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes