Functionalised polyhedral oligomeric silsesquioxane with encapsulated fluoride – first observation of fluxional Si⋯F interactions in POSS

Author:

Laird Mathilde12345ORCID,Totée Cédric12345,Gaveau Philippe12345,Silly Gilles12345,Van der Lee Arie67234ORCID,Carcel Carole12345ORCID,Unno Masafumi891011ORCID,Bartlett John R.121314ORCID,Wong Chi Man Michel12345ORCID

Affiliation:

1. ICGM Univ. Montpellier

2. CNRS

3. ENSCM

4. Montpellier

5. France

6. Institut Européen des Membranes

7. Univ. Montpellier

8. Department of Chemistry and Chemical Biology

9. Graduate School of Science and Technology

10. Gunma University

11. Japan

12. Western Sydney University

13. Penrith

14. Australia

Abstract

The first observation of fluxional covalent Si⋯F interactions in functionalised T8-F cage silsesquioxanes containing an encapsulated fluoride is reported.

Funder

Ministère de l'Enseignement Supérieur et de la Recherche

Japan Student Services Organization

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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