Hidden entropic contribution in the thermodynamics of molecular complexation
Author:
Affiliation:
1. Department of Physics
2. Sevastopol State University
3. Sevastopol 299053
4. Russian Federation
5. Department of Biology and Chemistry
Abstract
It has become an axiom that the thermodynamic analysis of non-covalent molecular complexation is intrinsically model-dependent, i.e. the set of implicitly or explicitly introduced assumptions may strongly affect the thermodynamic parameters.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP06738C
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