Transition metal-free cyclobutene rearrangement in fused naphthalen-1-ones: controlled access to functionalized quinones

Author:

Herrera Fernando12345,Luna Amparo12345ORCID,Fernández Israel67589ORCID,Almendros Pedro101112139ORCID

Affiliation:

1. Grupo de Lactamas y Heterociclos Bioactivos

2. Departamento de Química Orgánica

3. Unidad Asociada al CSIC

4. Facultad de Química

5. Universidad Complutense de Madrid

6. Departamento de Química Orgánica I and Centro de Innovación en Química Avanzada (ORFEO-CINQA)

7. Facultad de CC. Químicas

8. 28040-Madrid

9. Spain

10. Instituto de Química Orgánica General

11. IQOG-CSIC

12. Juan de la Cierva 3

13. 28006-Madrid

Abstract

The divergent preparation of 1,4-naphthoquinones and tetraphene-7,12-diones, which bear the ABCD-ring of landomycins, has been accomplished directly through oxidative reorganization of previously non-isolable cyclobuta[a]naphthalen-4(2H)-ones.

Funder

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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