Relevant electronic interactions related to the coordination chemistry of tetracyanometallates. An XPS study-Reference-Cited by-同舟云学术

Relevant electronic interactions related to the coordination chemistry of tetracyanometallates. An XPS study

Published:2019 Issue:46 Volume:43 Page:18384-18393
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Cano A.¹²³⁴⁵^ORCID,Monroy I.¹²³⁴⁵^ORCID,Ávila M.¹²³⁴⁵^ORCID,Velasco-Arias D.⁶²³⁴⁵^ORCID,Rodríguez-Hernández J.⁷⁸⁵^ORCID,Reguera E.¹²³⁴⁵^ORCID

Affiliation:

1. Instituto Politécnico Nacional

2. Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada

3. Unidad Legaria

4. Ciudad de México

5. Mexico

6. CONACyT-Instituto Politécnico Nacional

7. Centro de Investigación en Química Aplicada

8. Saltillo

Abstract

In the K₂[M(CN)₄]·xH₂O (M = Ni, Pd, Pt) series, the CN ligand is found to donate electron density to the K ion, which is detected as a decrease in the K 2p BE. The charge donated is proportional to that removed from the inner metal (M) via π-back bonding.

Funder

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C9NJ04173G

Reference33 articles.

1. Screening Hofmann Compounds as CO2 Sorbents: Nontraditional Synthetic Route to Over 40 Different Pore-Functionalized and Flexible Pillared Cyanonickelates

2. 1-Methyl-2-Pyrrolidone: From Exfoliating Solvent to a Paramagnetic Ligand

3. Three structural modifications in the series of layered solids T(H2O)2[Ni(CN)4]·xH2O with T=Mn, Co, Ni: Their nature and crystal structures