Phenothiazine cyclic hexamers: synthesis, properties, and complexation behavior with C60

Author:

Yamamoto Koji1ORCID,Tsutsui Kanta2,Tanuma Miho2,Ito Kaname2,Wakamatsu Kan3ORCID,Yamamoto Koji4,Nakamura Yosuke2ORCID

Affiliation:

1. Department of Pharmaceutical Sciences, Shujitsu University, 1-6-1 Nishigawara, Okayama 703-8516, Japan

2. Division of Molecular Science, Faculty of Science and Technology, Gunma University, 1-5-1 Tenjin-cho, Kiryu, Gunma 376-8515, Japan

3. Department of Chemistry, Faculty of Science, Okayama University of Science, 1-1 Ridaicho, Kita-ku, Okayama 700-0005, Japan

4. Department of Applied Chemistry, National Defense Academy, 1-10-20 Hashirimizu, Yokosuka, Kanagawa 239-8686, Japan

Abstract

Phenothiazine cyclic hexamers were synthesized, and effects of the cyclic structure and N-substituents were disclosed. The hexamer formed a Saturn-like 1 : 1 complex with C60via mainly S–π interactions.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

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