Negative linear compressibility exhibited by the hybrid perovskite [(NH2)3C]Er(HCO2)2(C2O4)-Reference-Cited by-同舟云学术

Negative linear compressibility exhibited by the hybrid perovskite [(NH₂)₃C]Er(HCO₂)₂(C₂O₄)

Published:2024 Issue:24 Volume:60 Page:3271-3274
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Hitchings Thomas J.¹^ORCID,Scatena Rebecca²,Allan David R.²^ORCID,Cairns Andrew B.³⁴^ORCID,Saines Paul J.¹^ORCID

Affiliation:

1. School of Chemistry and Forensic Science, Ingram Building, University of Kent, Canterbury, Kent, CT2 7NH, UK

2. Diamond Light Source, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Fermi Avenue, Didcot, OX11 0DE, UK

3. Department of Materials, Imperial College London, Royal School of Mines, Exhibition Road, SW7 2AZ, UK

4. London Centre for Nanotechnology, Imperial College London, London SW7 2AZ, UK

Abstract

Two hybrid perovskites under pressure exhibit drastically different mechanical behaviour, with one expanding in one direction whilst the other compresses conventionally.

Funder

Diamond Light Source

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC06208B

Reference36 articles.

1. Near Zero Area Compressibility in a Perovskite-Like Metal–Organic Frameworks [C(NH2)3][Cd(HCOO)3]

2. Polymorphism in Molecular Solids: An Extraordinary System of Red, Orange, and Yellow Crystals

3. Tunable Zero Linear Compressibility under a Rational Designed Mechanism of Modular “Dumbbell”: A Density Functional Theory Study

4. Adjustable uniaxial zero thermal expansion and zero linear compressibility in unique hybrid semiconductors: the role of the organic chain

5. Negative linear compressibility