Synthesis of atropisomeric phosphino-triazoles and their corresponding gold(<scp>i</scp>) complexes-Reference-Cited by-同舟云学术

Synthesis of atropisomeric phosphino-triazoles and their corresponding gold(i) complexes

Published:2023 Issue:14 Volume:10 Page:3460-3466
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhao Yiming¹^ORCID,Meloni Fernanda¹^ORCID,Male Louise¹^ORCID,Le Duff Cécile S.¹,Brittain William D. G.²^ORCID,Buckley Benjamin R.³^ORCID,Fossey John S.¹^ORCID

Affiliation:

1. School of Chemistry, University of Birmingham, Edgbaston, Birmingham, West Midlands, B15 2TT, UK

2. Department of Chemistry, Durham University, South Road, Durham DH1 3LE, UK

3. Department of Chemistry, Loughborough University, Loughborough, Leicestershire, LE11 3TU, UK

Abstract

The synthesis of atropisomeric phosphino-triazoles through a CuAAC approach is disclosed. Gold(i) chloride complexes of single-enantiomer phosphines were then prepared and again demonstrated to be conformationally stable.

Funder

University of Birmingham

Durham University

Loughborough University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO00322A

Reference46 articles.

1. Recent Advances in Catalytic Asymmetric Construction of Atropisomers

2. Atropisomerism in the Pharmaceutically Relevant Realm

3. Atropisomers beyond the C–C axial chirality: Advances in catalytic asymmetric synthesis

4. A twist of nature – the significance of atropisomers in biological systems

5. Development of Ar-BINMOL-Derived Atropisomeric Ligands with Matched Axial and sp3Central Chirality for Catalytic Asymmetric Transformations

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